141.泭Zhu, Y.-L.; Lee, W.-C. C.; Zhang, X. P. Catalytic Metalloradical System for Radical 1,6-C(sp3)H Amination with Concurrent Control of Site-, Chemo-, and Enantio-selectivity泭J. Am. Chem. Soc.泭2025, 147, XXXXXXXX. []

140.泭Lee, W.-C. C.; Zhang, X. P. Metalloradical Catalysis: General Approach for Controlling Reactivity and Selectivity of Homolytic Radical Reactions泭Angew. Chem. Int. Ed.泭2024,泭63, e202320243. []

139.泭Lee, W.-C. C.; Zhang, X. P. Asymmetric Radical Aziridination of Alkenes泭Trends Chem.泭2024,泭6,泭9596. [][]

138.泭Xu, H.; Wang, D.-S.; Zhu, Z.-Y.; Deb, A.; Zhang, X. P. New Mode of Asymmetric Induction for Enantioselective Radical泭N-Heterobicyclization via Kinetically Stable Chiral Radical Center泭Chem泭2024,泭10,泭283298. []

137.泭Lee, W.-C. C.; Zhang, X. P. Iron(III) Porphyrin Complexes as Metalloradical Catalysts泭Nat. Chem.泭2023,泭15,泭14991500. []

136.泭Lee, W.-C. C.; Wang, D.-S.; Zhu, Y.-L.; Zhang, X. P. Iron(III)-Based Metalloradical Catalysis for Asymmetric Cyclopropanation via a Stepwise Radical Mechanism泭Nat. Chem.泭2023,泭15,泭15691580. [] []

135.泭Lee, W.-C. C.;泭Wang, J.-Y.;泭Zhu, Y.-L.; Zhang, X. P. Asymmetric Radical Bicyclization for Stereoselective Construction of Tricyclic Chromanones and Chromanes with Fused Cyclopropanes泭J. Am. Chem. Soc.泭2023,泭145,泭1162211632. [] [] []


134.泭Xu, P.; Xie, J.-J.; Wang, D.-S.; Zhang, X. P. Metalloradical Approach for Concurrent Control in Intermolecular Radical Allylic CH Amination泭Nat. Chem.泭2023,泭15,泭498507. []

133.泭Wang, D.-S.; Zhang, X. P. Oxidation: CN Bond Formation by Oxidation (Aziridines) In Comprehensive Chirality (Second Edition); Cossy, J. Ed.; Elsevier,泭2022, DOI:泭. []

132.泭Novaes, L. F. T.; Wang, Y.; Liu, J.-J.; Riart-Ferrer, X.; Lee, W.-C. C.; Fu, N.-K.; Zhang, X. P.; Lin, S. Electrochemical Diazidation of Alkenes Catalyzed by Manganese Porphyrin Complexes with Second-Sphere Hydrogen-Bond Donors泭ACS Catal.泭2022,泭12,泭1410614112. []

131.泭Lang, K.; Hu, Y.; Lee, W.-C. C.; Zhang, X. P. Combined Radical and Ionic Approach for The Enantioselective Synthesis of泭帣-Functionalized Amines from Alcohols泭Nat. Synth.泭2022,泭1,泭548557. [] [] []

130.泭泭Lee, W.-C. C.; Zhang, X. P. Asymmetric Radical Cyclopropanation of Alkenes泭Trends Chem.泭2022,泭4,泭850851. []

129.泭泭Ke, J.; Lee, W.-C. C.; Wang, X.-X.; Wang, Y.; Wen, X.; Zhang, X. P. Metalloradical Activation of In Situ-Generated泭帢泭-Alkynyldiazomethanes for Asymmetric Radical Cyclopropanation of Alkenes泭J. Am. Chem. Soc.泭2022,泭144, 23682378. []

128.泭泭Wang, X.-X.; Zhang, X. P. Catalytic Radical Approach for Selective Carbene Transfers via Cobalt(II)-Based Metalloradical Catalysis In泭Transition Metal-Catalyzed Carbene Transformations泭2022, 25-66. []

127.泭泭Wang, J.-Y.; Xie, J.-J.; Lee, W.-C. C.; Wang, D.-S.; Zhang, X. P. Radical Differentiation of Two Ester Groups in Unsymmetrical Diazomalonates for Highly Asymmetric Olefin Cyclopropanation泭Chem Catal.泭2022,泭2, 330344. [] [] []

126.泭泭Zhang, W.-J.; Nafady, A.; Shan, C.; Wojtas, L.; Chen, Y.-S.; Cheng, Q.-G.; Zhang, X. P.; Ma, S.-Q. Functional Porphyrinic Metal-Organic Framework as a New Class of Heterogeneous Halogen Bond Donor Catalyst泭Angew. Chem. Int. Ed.泭2021,泭60, 2431224317. []

125.泭泭Xie, J.-J.; Xu, P.; Zhu, Y.-L.; Wang, J.-Y.; Lee, W.-C. C.; Zhang, X. P. New Catalytic Radical Process Involving 1,4-Hydrogen Atom Abstraction: Asymmetric Construction of Cyclobutanones泭J. Am. Chem. Soc.泭2021,泭143, 11670-11678. []

124.泭泭Wang, X.-X.; Ke, J.; Zhu, Y.-L.; Deb, A.; Xu, Y.-J.; Zhang, X. P. Asymmetric Radical Process for General Synthesis of Chiral Heteroaryl Cyclopropanes泭J. Am. Chem. Soc.泭2021,泭143, 11121-11129. []

123.泭泭Zhang, C.-Z.; Wang, D.-S.; Lee, W.-C. C.; McKillop, A. M.; Zhang, X. P. Controlling Enantioselectivity and Diastereoselectivity in Radical Cascade Cyclization for Construction of Bicyclic Structures泭J. Am. Chem. Soc.泭2021,泭143, 11130-11140. []

122.泭泭Lee, W.-C. C. Metalloradical Catalysis: A Radically Different Approach for Molecular Construction泭Chem泭2021,泭7, 1402-1404. []

121.泭泭Lee, W.-C. C.; Wang, D.-S.; Zhang, C.-Z.; Xie, J.-J.; Li, B.; Zhang, X. P. Asymmetric Radical Cyclopropanation of Dehydroaminocarboxylates: Stereoselective Synthesis of Cyclopropyl泭帢-Amino Acids泭Chem泭2021,泭7, 1588-1601. []

120.泭泭Magnuson, Z. L.; Cheng, Q.-G.; Zhang, W.-J.; Chen, Y.-S.; Wojtas, L.; Nafady, A.; Al-Enizi, A. M.; Larsen, R. W.; Zhang, X. P.; Ma, S.-Q. Two Manganese Metalloporphyrin Frameworks Constructed from a Custom-Designed Porphyrin Ligand Exhibiting Selective Uptake of CO2泭over CH4泭and Catalytic Activity for CO2泭Fixation泭Cryst. Growth Des.泭2021,泭21, 27862792. []

119.泭泭Riart-Ferrer, X.; Sang, P.; Tao, J.-R.; Xu, H.; Jin, L.-M.; Lu, H.-J.; Cui, X.; Wojtas, L.; Zhang, X. P. Metalloradical Activation of Carbonyl Azides for Enantioselective Radical Aziridination泭Chem泭2021,泭7, 11201134. []

118.泭泭Lang, K.; Li, C.-Q.; Kim, I.; Zhang, X. P. Enantioconvergent Amination of Racemic Tertiary C-H Bonds泭J. Am. Chem. Soc.泭2020,泭142, 2090220911. []

117.泭泭Jin, L.-M.; Xu, P.; Xie, J.-J.; Zhang, X. P. Enantioselective Intermolecular Radical CH Amination泭J. Am. Chem. Soc.泭2020,泭142, 2082820836. []

116.泭泭Hu, Y.; Lang, K.; Li, C.-Q.; Gill, J. B.; Kim, I.; Lu, H.-J.; Fields, K. B.; Marshall, M. K.; Cheng, Q.-G.; Cui, X.; Wojtas, L.; Zhang, X. P. Enantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical CH Amination泭J. Am. Chem. Soc.泭2019,泭141, 18160-18169. []

115.泭泭Lang, K.; Torker, S.; Wojtas, L.; Zhang, X. P. Asymmetric Induction and Enantiodivergence in Catalytic Radical CH Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution泭J. Am. Chem. Soc.泭2019,泭141, 1238812396. []

114.泭泭Hu, Y.; Lang, K.; Tao, J.-R.; Marshall, M. K.; Cheng, Q.-G.; Cui, X.; Wojtas, L.; Zhang, X. P. Next-Generation D2-Symmetric Chiral Porphyrins for Cobalt(II)-Based Metalloradical Catalysis: Catalyst Engineering by Distal Bridging泭Angew. Chem. Int. Ed.泭2019,泭58, 26702674. []

113.泭泭Li, C.-Q.; Lang, K.; Lu, H,-J.; Hu, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. Catalytic Radical Process for Enantioselective Amination of C(sp3)-H Bonds泭Angew. Chem. Int. Ed.泭2018,泭57, 1683716841. []

112.泭泭Wen, X.; Wang, Y.; Zhang, X. P. Enantioselective Radical Process for Synthesis of Chiral Indolines by Metalloradical Alkylation of Diverse C(sp3)-H Bonds泭Chem. Sci.泭2018,泭9, 50825086. []

111.泭泭Wang, Y.; Wen, X.; Cui, X.; Zhang, X. P. Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation泭J. Am. Chem. Soc.泭2018,泭140, 47924796. []

110.泭泭Wang, Y.; Zhang, X. P. [Co(3,5-Di-t-Bu-QingPhyrin)]泭e-EROS, John Wiley & Sons,泭2018;泭DOI: 10.1002/047084289X.rn02204. []

109.泭泭Wang, Y.; Zhang, X. P. [Co(3,5-Di-t-Bu-Xu(2-Naph)Phyrin)]泭e-EROS, John Wiley & Sons,泭2018;泭DOI: 10.1002/047084289X.rn02203. []

108.泭泭Wang, Y.; Zhang, X. P. [Co(3,5-Di-t-Bu-ChenPhyrin)]泭e-EROS, John Wiley & Sons,泭2018;泭DOI: 10.1002/047084289X.rn02202. []

107.泭泭Wang, Y.; Zhang, X. P. [Co(3,5-Di-t-Bu-IbuPhyrin)]泭e-EROS, John Wiley & Sons,泭2018;泭DOI: 10.1002/047084289X.rn02201. []

106.泭泭Wang, Y.; Zhang, X. P. [Co(2,6-DiMeO-ZhuPhyrin)]泭e-EROS, John Wiley & Sons,泭2018;泭DOI: 10.1002/047084289X.rn02200. []

105.泭泭Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis泭J. Am. Chem. Soc.泭2017,泭139, 91649167. []

104.泭泭Xu, X.; Wang, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. Metalloradical Activation of泭帢-Formyldiazoacetates for Catalytic Asymmetric Radical Cyclopropanation of Alkenes泭Chem. Sci.泭2017,泭8, 43474351. []

103.泭泭Wang, Y.; Wen, X.; Cui, X.; Wojtas, L.; Zhang, X. P. Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis泭J. Am. Chem. Soc.泭2017,泭139, 10491052. []

102.泭泭Pegis, M. L.; McKeown, B. A.; Kumar, N.; Lang, K.; Wasylenko, D. J.; Zhang, X. P.; Raugei, S.; Mayer, J. M. Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions泭ACS Cent. Sci.泭2016,泭2, 850856. []

101.泭泭Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides via Co(II)-Based Metalloradical Catalysis: Effective Construction of Strained heterobicyclic Structures泭Angew. Chem. Int. Ed.泭2016,泭55, 1160411608. []

100.泭泭Lu, H.-J.; Lang, K.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. Intramolecular 1,5-C(sp3)H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides泭Chem. Sci.泭2016,泭7, 69346939. []

99.泭泭Liu, Q.-J.; Wang, L.-J.; Kang, Q.-K.; Zhang, X. P.; Tang, Y. Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals泭Angew. Chem. Int. Ed.泭2016,泭55, 92209223. []

98.泭泭Cui, X.; Zhang, X. P. CC Bond Formation Using Carbenes In泭Science of Synthesis: Catalytic Transformations via CH Activation泭series; eds. Yu, J. -Q.; Thieme,泭2016, Vol. 2, pp. 6394. []

97.泭泭Liu, Q.-J.; Yan, W.-G.; Wang, L.-J.; Zhang, X. P.; Tang, Y. One-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles泭Org. Lett.泭2015,泭17, 40144017. []

96.泭泭Goswami, M.; Lyaskovskyy, V.; Domingos, S. R.; Buma, W. J.; Woutersen, S.; Troeppner, O.; Ivanovic-Burmazovic, I.; Lu, H.-J.; Cui, X.; Zhang, X. P.; Reijerse, E. J.; DeBeer S.; van Schooneveld, M. M.; Pfaff, F.; Ray, K.; de Bruin, B. Characterization of Porphyrin-Co(III)-Nitrene Radical Species Relevant in Catalytic Nitrene Transfer Reactions泭J. Am. Chem. Soc.泭2015,泭137, 54685479. []

95.泭泭Subbarayan, V.; Jin, L.-M., Cui, X.; Zhang, X. P. Room Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis泭Tetrahedron Lett.泭2015,泭56, 34313434. []

94.泭泭Cui, X.; Xu, X.; Jin, L.-M.; Wojtas, L.; Zhang, X. P. Stereoselective Radical CH Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis泭Chem. Sci.泭2015.泭6, 12191224. []

93.泭泭Jin, C.-Y., Decker, A. M.; Huang, X.-P.; Gilmour, B. P.; Blough, B. E.; Roth, B. L.; Hu, Y.; Gill, J. B.; Zhang, X. P. Synthesis, Pharmacological Characterization, and Structure-Activity Relationship Studies of Small Molecular Agonists for the Orphan GPR88泭ACS Chem. Neurosci.泭2014,泭5, 576587. []

92.泭泭Lu, H.-J.; Li, C.-Q.; Jiang, H.-L.; Lizardi, C. L.; Zhang, X. P. Chemoselective Amination of Propargylic C(sp3)H Bonds via Co(II)-Based Metalloradical Catalysis泭Angew. Chem. Int. Ed.泭2014,泭53, 70287032. []

91.泭泭Tao, J.-R.; Jin, L.-M.; Zhang, X. P. Synthesis of Chiral泭N-Phosphoryl Aziridines through Enantioselective Aziridination of Alkenes With Phosphoryl Azide via Co(II)-Based Metalloradical Catalysis泭Beilstein J. Org. Chem.泭2014,泭10, 12821289. []

90.泭泭Ruppel, J. V.; Cui, X.; Xu, X.; Zhang, X. P. Stereoselective Intramolecular Cyclopropanation of alpha-Diazoacetates via Co(II)-Based Metalloradical Catalysis泭Org. Chem. Front.泭2014,泭1, 515520. []

89.泭泭Jin, L.-M.; Lu, H.-J.; Cui, Y.; Lizardi, C. L.; Arzua, T. N.; Wojtas, L.; Cui, X.; Zhang, X. P. Selective Radical Amination of Aldehydic C(sp2)H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of泭N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions泭Chem. Sci.泭2014,泭5, 24222427. []

88.泭泭Paul, N. D.; Mandal, S.; Otte, M.; Cui, X.; Zhang, X. P.; de Bruin, B. A Metalloradical Approach to泭2H-Chromenes泭J. Am. Chem. Soc.泭2014,泭136, 10901096. []

87.泭泭Cui, X.; Zhang, X. P. Asymmetric CH Functionalization by Transition Metal-Catalyzed Carbene Transfer Reactions In泭Comprehensive Organic Synthesis II (Second Edition)泭Eds. Knochel, P.; Molander, G.; Amsterdam: Elsevier,泭2014, Vol. 7, pp. 86120. []
86.泭泭Maza, W. A.; Vetromile, G. M.; Kim, C.-S.; Xu, X.; Zhang, X. P.; Larsen, R. W. Spectroscopic Investigation of the Noncovalent Association of the Nerve Agent Simulant Diisopropyl Methylphosphonate (DIMP) with Zinc(II)porphyrins泭J. Phys. Chem. A.泭2013,泭117, 1130811315. []

85.泭泭Xu, X.; Zhu, S.-F.; Cui, X.; Wojtas, L.; Zhang, X. P. Cobalt(II)-Catalyzed Asymmetric Olefin Cyclopropanation with a-Ketodiazoacetates泭Angew. Chem. Int. Ed.泭2013,泭52, 1185711861. [] [Highlighted in泭]

84.泭泭Paul, N. D.; Lu, H.-J.; Zhang, X. P.; de Bruin, B. Carbene Radicals in Cobalt(II) Porphyrin-Catalyzed Carbene Carbonylation Reactions: A Catalytic Approach to Ketenes泭Chem. Eur. J.泭2013,泭19, 1295312958. []

83.泭泭Liu, L.; Xie, H.; Bostic, H. E.; Jin, L.-M.; Best, D. B.; Zhang, X. P.; Zhan, W. Effects of Oriented Surface Dipole on Photoconversion Efficiency in an Alkane/Lipid-Hybrid-Bilayer-Based Photovoltaic Model System泭ChemPhysChem泭2013,泭14, 27772785. []
82.泭泭Cui, X.; Zhang, X. P. Cobalt-Mediated Carbene Transfer Reactions In泭Contemporary Carbene Chemistry; eds. Moss, R. A.; Doyle, M. P.; John Wiley & Sons,泭2013, Chapter 15, 491525. []
81.泭泭Jin, L.-M.; Xu, X.; Lu, H.; Cui, X.; Wojtas, L.; Zhang, X. P. Effective Synthesis of Chiral泭N-Fluoroaryl Aziridines via Enantioselective Aziridination of Alkenes with Fluoroaryl Azides泭Angew. Chem. Int. Ed.泭2013,泭52, 53095313. [] [Highlighted in泭] [Highlighted in泭]

80.泭泭Cui, X.; Xu, X.; Wojtas, L.; Kim, M. M.; Zhang, X. P. Regioselective Synthesis of Multisubstituted Furans via Metalloradical Cyclization of Alkynes with alpha-Diazocarbonyls: Construction of Functionalized alpha-Oligofurans泭J. Am. Chem. Soc.泭2012,泭134, 1998119984. [] [Highlighted in泭] [Highlighted in泭]

79.泭泭Lu, H.-J.; Jiang, H.-L.; Hu, Y.; Wojtas, L.; Zhang, X. P. Stereoselective Radical Amination of Electron-Deficient C(sp3)H Bonds by Co(II)-Based Metalloradical Catalysis: Synthesis of alpha-Amino Acid Derivatives via alpha-CH Amination of Esters and Amides泭Org. Lett.泭2012,泭14, 51585161. []

78.泭泭Meng, L.; Cheng, Q.; Kim, C.-S.; Gao, W.-Y.; Wojtas, L.; Chen, Y.-S.; Zaworotko, M. J.; Zhang, X. P.; Ma, S.-Q. Crystal Engineering of a Microporous, Catalytically Active fcu Topology MOF Using a Custom-Designed Metalloporphyrin Linker泭Angew. Chem. Int. Ed.泭2012,泭51, 1008210085. [] [Selected as泭]

77.泭泭Jiang, H.-L.; Zhang, X. P. Oxidation: CN Bond Formation by Oxidation (Aziridines) In泭Comprehensive Chirality; eds. Carreira, E. M.; Yamamoto, H.; Amsterdam: Elsevier,泭2012, Vol. 5, pp. 168182. []泭
76.泭泭Wang, X.-S.; Chrzanowski, M.; Gao, W.-Y.; Kim, C.-S.; Wojtas, L.; Chen, Y.-S.; Zhang, X. P.; Ma, S.-Q. Quest for Highly泭Porous Metal-Metalloporphyrin Framework Based upon A Custom-Designed泭Octatopic Porphyrin Ligand泭Chem. Commun.泭2012,泭48, 71737175. []

75.泭泭Hu, Y.; Zhang, X. P. Selective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents泭Top. Curr. Res.泭2012,泭327, 147162. []
74.泭泭Zhu, S.-F.; Cui, X.; Zhang, X. P. Ligand Effect on Cobalt(II)-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Approaching High Stereoselectivity through Modular Design of D2-Symmetric Chiral Porphyrins泭Eur. J. Inorg. Chem.泭2012, 430434. []
73.泭泭Burda, W. N.; Fields, K. B.; Gill, J. B.; Burt, R.; Shepherd, M.; Zhang, X. P.; Shaw, L. N. Neutral Metallated and Meso-Substituted Porphyrins as Antimicrobial Agents Against Gram-Positive Pathogens泭Eur. J. Clin. Microbiol. Infect. Dis.泭2012,泭31, 327335. []
72.泭泭Cui, X.; Zhang, X. P. Iron(III) meso-Tetraphenylporphine Chloride泭e-EROS, John Wiley & Sons,泭2012;泭DOI: 10.1002/047084289X.rn01388. []
71.泭泭Wang, X.-S.; Meng, L.; Cheng, Q.-G.; Kim, C.-S.; Wojtas, L.; Chrzanowski, M.; Chen, Y.-S.; Zhang, X. P.; Ma, S.-Q. A Three-Dimensional Porous Metal-Metalloporphyrin Framework Consisting of Nanoscopic Polyhedral Cages with a High Density of Open Metal Sites泭J. Am. Chem. Soc.泭2011,泭133, 1632216325. []

70.泭泭Lu, H.-J.; Jiang, H.-L.; Hu, Y.; Wojtas, L.; Zhang, X. P. Chemoselective Intramolecular Allylic CH Amination over C=C Aziridination through Co(II)-Based Metalloradical Catalysis泭Chem. Sci.泭2011,泭2, 23612366. [] [Highlighted in泭]

69.泭泭Xu, X.; Lu, H.-J.; Ruppel, J. V.; Cui, X.; de Mesa, S. L.; Wojtas, L.; Zhang, X. P. Highly Asymmetric Intramolecular Cyclopropanation of Acceptor-Substituted Diazoacetates by Co(II)-Based Metalloradical Catalysis: Iterative Approach for Development of New Generation Catalysts泭J. Am. Chem. Soc.泭2011,泭133, 1529215295. [] [Highlighted in泭]

68.泭泭Lyaskovskyy, V.; Suarez, A. I. O.; Lu, H.-J.; Jiang, H.-L.; Zhang, X. P.; de Bruin, B. Mechanism of Cobalt(II) Porphyrin-Catalyzed CH Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of Cobalt(III)-Nitrene Key Intermediates泭J. Am. Chem. Soc.泭2011,泭133, 1226412273. []

67.泭泭Lu, H.-J.; Dzik, W. I.; Xu, X.; Wojtas, L.; de Bruin, B.; Zhang, X. P. Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation泭J. Am. Chem. Soc.泭2011,泭133, 85188521. []

66.泭泭Belof, J. L.; Cioce, C. R.; Xu, X.; Zhang, X. P.; Space, B.; Woodcock, H. L. Characterization of Tunable Radical Metal-Carbenes: Key Intermediates in Catalytic Cyclopropanation,泭Organometallics泭2011,泭30, 27392746. []

65.泭泭Dzik, W. I.; Zhang, X. P.; de Bruin, B. The Redox Non-Innocence of Carbene Ligands: Carbene Radicals in (Catalytic) C-C Bond Formation泭Inorg. Chem.泭泭2011,泭50, 98969903. []

64.泭泭Uygun, A.; Myjavcova, R.; Yavuz, A. G.; Ruppel. J. V.; Fields, K. B.; Frankhauser, A.; Zhang, X. P.; Bhethanbotla, V. R.; Bednar, P. Electrochemical Polymerization and Investigation of Properties of Poly(5-(4-aminophenylamino)-10,20-diphenylporphyrin)泭Electroanalysis泭2011,泭23, 11581167. []
63.泭泭Suarez, A. I. O.; Jiang, H.-L.; Zhang, X. P.; de Bruin, B. The Radical Mechanism of Cobalt(II) Porphyrin-Catalyzed Olefin Aziridination and the Importance of Cooperative H-Bonding泭Dalton Trans.泭泭2011,泭40, 56975705. []

62.泭泭Cui, X.; Xu, X.; Lu, H.-J.; Zhu, S.-F.; Wojtas, L.; Zhang, X. P. Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis泭J. Am. Chem. Soc.泭2011,泭133, 33043307. [] [Highlighted in泭]

61.泭泭Lu, H.-J.; Zhang, X. P. Catalytic CH Functionalization by Metalloporphyrins: Recent Development and Future Directions泭Chem. Soc. Rev.泭2011,泭40, 18991909. []

60.泭泭Fields, K. B.; Engle, J. T.; Sripothongnak, S.; Kim, C.-S.; Zhang, X. P.; Ziegler, C. J. Cobalt Carbaporphyrin-Catalyzed Cyclopropanation泭Chem. Commun.泭2011,泭47, 749. []泭泭

59.泭泭Lu, H.-J.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. Selective Intramolecular CH Amination via Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions泭Angew. Chem. Int. Ed.泭2010,泭49, 1019210196. [] [Selected as泭][Highlighted in泭]

58.泭泭Zhan, W.; Jiang, K.; Smith, M. D.; Bostic, H. E.; Best, M. D.; Auad, M. L.; Ruppel, J. V.; Kim, C.-S.; Zhang, X. P. Photocurrent Generation from Porphyrin/Fullerene Complexes Assembled in a Tethered Lipid Bilayer泭Langmuir泭2010, 26, 1567115679. []

57.泭泭Hilker, B.; Fields, K. B.; Stern, A.; Space, B.; Zhang, X. P.; Harmon, J. P. Dielectric Analysis of Poly(methyl methacrylate) Zinc(II) Mono-pinacolborane Diphenylporphyrin Composites泭Polymer泭2010, 51, 47904805. []

56.泭泭Zhu, S.-F.; Xu, X.; Perman, J. A.; Zhang, X. P. A General and Efficient Cobalt(II)-Based Catalytic System for Highly Stereoselective Cyclopropanation of Alkenes with a-Cyano-Diazoacetates泭J. Am. Chem. Soc.泭2010,泭132, 1279612799. [] [Highlighted in泭] [Highlighted in泭]

55.泭泭Dzik, W. I.; Xu, X.; Zhang, X. P.; Reek, J. N. H.; de Bruin, B. Carbene Radicals in CoII(por)-Catalyzed Olefin Cyclopropanation泭J. Am. Chem. Soc.泭2010,泭132, 1089110902. []

54.泭泭Lu, H.-J.; Tao, J.-R.; Jones, J. E.; Wojtas, L.; Zhang, X. P. Co(II)-Catalyzed Intramolecular CH Amination of Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates泭Org. Lett.泭2010,泭12,泭12481251. [] [Highlighted in泭]

53.泭泭Lu, H.-J.; Subbarayan, V.; Tao, J.; Zhang, X. P. Cobalt-Catalyzed Intermolecular Benzylic CH Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)泭Organometallics泭2010,泭29, 389393. []

52.泭泭Ruppel, J. V.; Fields, K. B.; Snyder, N. L.; Zhang, X. P. Metalloporphyrin-Catalyzed Asymmetric Atom/Group Transfer Reactions In泭Handbook of Porphyrin Science; eds. Kadish, K. M.; Smith, K. M.; Guilard, R.; World Scientific,泭2010, Vol. 10, Chapter 43, pp. 184. []
51.泭泭Fields, K. B.; Ruppel, J. V.; Snyder, N. L.; Zhang, X. P. Porphyrin Functionalization via Carbon-Heteroatom Cross-Coupling Reactions In泭Handbook of Porphyrin Science; eds. Kadish, K. M.; Smith, K. M.; Guilard, R.; World Scientific,泭2010, Vol. 3, Chapter 13, pp. 367428. []
50.泭泭Subbarayan, V.; Ruppel, J. V.; Zhu, S.-F.; Perman, J. A.; Zhang, X. P. Highly Asymmetric Cobalt-Catalyzed Aziridination of Alkenes with Trichloroethoxysulfonyl Azide (TcesN3)泭Chem. Commun.泭2009,泭42664268. []

49.泭泭Ruppel, J. V.; Gauthier, T. J.; Snyder, N. L.; Perman, J. A.; Zhang, X. P. Asymmetric Cobalt-Catalyzed Cyclopropanation with Succinimidyl Diazoacetate: General Synthesis of Optically Active Cyclopropyl Carboxamides泭Org. Lett.泭2009,泭11, 22732276. [] [Highlighted in泭]泭

48.泭泭Zhu, S.-F.; Zhang, X. P. Cobalt(II) Acetate泭e-EROS, John Wiley & Sons,泭2009; DOI: 10.1002/047084289X.rc182.pub2. []
47.泭泭Zhu, S.-F.; Perman, J. A.; Zhang, X. P. Acceptor/Acceptor-Substituted Diazo Reagents for Carbene Transfers: Cobalt-Catalyzed Asymmetric (Z)-Cyclopropanation of Alkenes with a-Nitro-Diazoacetates泭Angew. Chem. Int. Ed.泭2008, 47, 84608463. [] [Highlighted in泭] [Highlighted in泭]

46.泭泭Jones, J. E.; Ruppel, J. V.; Gao, G.-Y.; Thomas, M. M.; Zhang, X. P. Cobalt-Catalyzed Asymmetric Olefin Aziridination with Diphenylphosphoryl Azide泭J. Org. Chem.泭2008,泭73, 72607265. []

45.泭泭Gao, G.-Y.; Ruppel, J. V.; Fields, K. B.; Xu, X.; Chen, Y.; Zhang, X. P. Synthesis of Diporphyrins via Palladium-Catalyzed CO Bond Formation: Effective Access to Chiral Diporphyrins泭J. Org. Chem.泭2008,泭73, 48554858. []

44.泭泭Ruppel, J. V.; Jones, J. E.; Huff, C. A.; Kamble, R. M.; Chen, Y.; Zhang, X. P. A Highly Effective Cobalt Catalyst for Olefin Aziridination with Azides: Hydrogen Bonding-Guided Catalyst Design泭Org. Lett.泭2008,泭10, 19951998. []

43.泭泭Zhu, S.; Ruppel, J. V.; Lu, H.; Wojtas, L.; Zhang, X. P. Cobalt-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Rigidification and Polarization of Ligand Chiral Environment via Hydrogen Bonding and Cyclization泭J.泭Am. Chem. Soc.泭2008,泭130, 50425043. [] [Highlighted in泭] [Highlighted in泭]

42.泭泭Gao, G. Y.; Ruppel, J. V.; Allen, D. B.; Chen, Y.; Zhang, X. P. Synthesis of beta-Functionalized Porphyrins via Palladium-Catalyzed CarbonHeteroatom Bond Formations: Expedient Entry into beta-Chiral Porphyrins泭J. Org. Chem.泭2007,泭72, 90609066. []

41.泭泭Harden, J. D.; Ruppel, J. V.; Gao, G.-Y.; Zhang, X. P. Cobalt-Catalyzed Intermolecular CH Amination with Bromamine-T as Nitrene Source泭Chem. Comm.泭2007,泭46444646. []

40.泭泭Ruppel, J. V.; Kamble, R. M.; Zhang, X. P. Cobalt-Catalyzed Intramolecular CH Amination with Arylsulfonyl Azides泭Org. Lett.泭2007,泭9, 48894892. []

39.泭泭Chen, Y.; Ruppel, J. V.; Zhang, X. P. Cobalt-Catalyzed Asymmetric Cyclopropanation of Electron-Deficient Olefins泭J.泭Am. Chem. Soc.泭2007,泭129, 1207412075. [] [Highlighted in泭] [Highlighted in泭] [Highlighted in泭]

38.泭泭Chen, Y.; Zhang, X. P. Asymmetric Cyclopropanation of Styrenes Catalyzed by Metal Complexes of泭D2-Symmetrical Chiral Porphyrin: Superiority of Cobalt over Iron泭J. Org. Chem.泭2007,泭72, 59315934. [] [Highlighted in泭]

37.泭泭Gao, G.-Y.; Jones, J. E.; Vyas, R.; Harden, J. D.; Zhang, X. P. Cobalt-Catalyzed Aziridination with Diphenylphosphoryl Azide (DPPA): Direct Synthesis of泭N-Phosphorous-Substituted Aziridines from Alkenes泭J. Org. Chem.泭2006,泭71, 66556658. []

36.泭泭Chen, Y.; Zhang, X. P. Trans Effect on Cobalt Porphyrin Catalyzed Asymmetric Cyclopropanation泭Synthesis泭2006,泭No.10, 16971700. (Invited Contribution to Special Topic) []

35.泭泭Gao, G.-Y.; Harden, J. D.; Zhang, X. P. Cobalt-Catalyzed General and Efficient Aziridination of Alkenes泭Org. Lett.泭2005,泭7, 31913193. []

34.泭泭Chen, Y.; Gao, G.-Y.; Zhang, X. P. Palladium-Mediated Synthesis of Novel泭meso-Chiral Porphyrins for Cobalt-Catalyzed Cyclopropanation泭Tetrahedron Lett.泭2005,泭46, 49654969. []

33.泭泭Baskaran, D.; Mays, J. W.; Zhang, X. P.; Bratcher, M. S. Carbon Nanotubes with Covalently Linked Porphyrin Antennae: Photoinduced Electron Transfer泭J.泭Am. Chem. Soc.泭2005,泭127, 69166917. []

32.泭泭Gao, G.-Y.; Colvin, A. J.; Chen, Y.; Zhang, X. P. Synthesis of泭meso-Arylsulfanyl- and Alkylsulfanyl-Substituted Porphyrins via Palladium-Mediated CS Bond Formation泭J. Org. Chem.泭2004,泭69, 88868892. []

31.泭泭Chen, Y.; Fields, K. B.; Zhang, X. P. Bromoporphyrins as Versatile Synthons for Modular Construction of Chiral Porphyrins: Cobalt-Catalyzed Highly Enantioselective and Diastereoselective Cyclopropanation泭J.泭Am. Chem. Soc.泭2004,泭126, 1471814719.泭[] [Highlighted in泭]

30.泭泭Vyas, R.; Gao, G.-Y.; Harden, J. D.; Zhang, X. P. Iron(III) Porphyrin-Catalyzed Aziridination of Alkenes with Bromamine-T as Nitrene Source泭Org. Lett.泭2004,泭6, 19071910. []

29.泭泭Gao, G.-Y.; Chen, Y.; Zhang, X. P. General Synthesis of泭meso-Amidoporphyrins via Palladium-Catalyzed Amidation泭Org. Lett.泭2004,泭6, 18371840. []

28.泭泭Chen, Y.; Zhang, X. P. Vitamin B12泭Derivatives as Natural Asymmetric Catalysts: Enantioselective Cyclopropanation of Alkenes泭J. Org. Chem.泭2004,泭69, 24312435.泭[]

27.泭泭Lee, M.-Y.; Chen, Y.; Zhang, X. P. General and Selective Olefination of Aldehydes and Ketones Catalyzed by a Cobalt(II) Porphyrin Complex泭Organometallics泭2003,泭22, 49054909.泭[]

26.泭泭Huang, L.; Chen, Y.; Gao, G.-Y.; Zhang, X. P. Diastereoselective and Enantioselective Cyclopropanation of Alkenes Catalyzed by Cobalt Porphyrins泭J. Org. Chem.泭2003,泭68, 81798184.泭[]

25.泭泭Gao, G.-Y.; Colvin, A. J.; Chen, Y.; Zhang, X. P. Versatile Synthesis of泭meso-Aryloxy- and Alkoxy-Substituted Porphyrins via Palladium-Catalyzed CO Cross-Coupling Reactions泭Org. Lett.泭2003,泭5, 32613264.泭[]

24.泭泭Gao, G.-Y.; Chen, Y.; Zhang, X. P. General and Efficient Synthesis of Arylamino- and Alkylamino-Substituted Diphenylporphyrins and Tetraphenylporphyrins via Palladium-Catalyzed Multiple Amination Reactions泭J. Org. Chem.泭2003,泭68, 62156221.泭[]

23.泭泭Chen, Y.; Huang, L.; Zhang, X. P. Acid-Promoted Olefination of Ketones by Iron(III) Porphyrin Complex泭Org. Lett.泭2003,泭5, 24932496.泭[]

22.泭泭Chen, Y.; Huang, L.; Zhang, X. P. Efficient and Stereoselective Synthesis of beta-Trifluoromethyl-alpha, beta-Unsaturated Esters via Iron(III) Porphyrin-Catalyzed Olefination of Ketones泭J. Org. Chem.泭2003,泭68, 59255929.泭[]

21.泭泭Chen, Y.; Zhang, X. P. Facile and Efficient Synthesis of泭meso-Arylamino- and Alkylamino-Substituted Porphyrins via Palladium-Catalyzed Amination泭J. Org. Chem.泭2003,泭68, 44324438.泭[]

20.泭泭Chen, Y.; Huang, L.; Ranade, M. A.; Zhang, X. P. Iron(III) and Ruthenium(II) Porphyrin Complexes-Catalyzed Selective Olefination of Aldehydes with Ethyl Diazoacetate泭J. Org. Chem.泭2003,泭68, 37143717.泭[]

19.泭泭Cui, W.; Zhang, X. P.; Wayland, B. B. Bimetallo-Radical Carbon-Hydrogen Bond Activation of Methanol and Methane泭J.泭Am. Chem. Soc.泭2003,泭125, 49944995.泭[]
18.泭泭Yin, J-J.; Rainka, M. P.; Zhang, X.-X.; Buchwald, S. L. A Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand Coordination泭J.泭Am. Chem. Soc.泭2002,泭124,泭11621163. []
17.泭泭Zhang, X.-X.; Harris, M. C.; Sadighi, J. P.; Buchwald, S. L. The Use of Palladium Chloride as A Precatalyst for the Amination of Aryl Bromides泭Can.泭J. Chem.泭2001,泭79, 17991805. []
16.泭泭Zhang, X.-X.; Buchwald, S. L. Efficient Synthesis of泭N-Aryl-Aza-Crown Ethers via Palladium-Catalyzed Amination泭J. Org. Chem.泭2000,泭65, 80278031. []
15.泭泭Zhang, X.-X.; Lippard, S. J. A Mixed-Valent Heptairon Chloride Cluster Supported by the Porphyrin-Linked Dicarboxylate Ligand PDK泭Inorg. Chem.泭2000,泭39, 43884389. []
14.泭泭Zhang, X.-X.; Wayland, B. B. Sterically Demanding Diporphyrin Ligands and Rhodium(II) Porphyrin Bimetalloradical Complexes泭Inorg. Chem.泭2000,泭39, 53183525. []
13.泭泭Zhang, X.-X.; Sadighi, J. P.; Mackewitz, T. W.; Buchwald, S. L. Efficient Synthesis of Well-Defined, High Molecular Weight, and Processible Polyanilines under Mild Conditions via Palladium-Catalyzed Amination泭J.泭Am. Chem. Soc.泭2000,泭122, 76067607. []
12.泭泭Zhang, X.-X.; Lippard, S. J. Synthesis of PDK, a Novel Porphyrin-Linked Dicarboxylate Ligand泭J.泭Org. Chem.泭2000,泭65, 52985305. []
11.泭泭Zhang, X.-X.; Fuhrmann, P.; Lippard, S. J. Synthesis And Triiron Complexes of PDK, A New Porphyrin-Linked Dicarboxylate Ligand泭J.泭Am. Chem. Soc.泭1998,泭120, 1026010261. []
10.泭泭Zhang, X.-X.; Parks, F. P.; Wayland, B. B. One-Electron Activation of CO by a Rhodium(II) Porphyrin Bimetalloradical Complex: Concerted Reactions of Two Metalloformyl Radicals ((MCO)繚)泭J.泭Am. Chem. Soc.泭1997,泭119, 79387944. []
9.泭泭Del Rossi, K. J.; Zhang, X.-X.; Wayland, B. B. Reactions of C-H Bonds in Organic Oxygenates with Octaethylporphyrinato Rhodium(II) and Iridium(II) Dimers泭J. Organomet. Chem.泭1995,泭504, 4756. []
8.泭泭Zhang, X.-X.; Wayland, B. B. Rhodium(II) Porphyrin Bimetalloradical Complexes: Preparation and Enhanced Reactivity with CH4泭and H2泭J. Am. Chem. Soc.泭1994,泭116, 78977898. []
7.泭泭Francesconi, L. C.; Yang, Y. Y.; Kung, M. P.; Zhang, X.-X.; Billings, J.; Guo, Y. Z.; Kung, H. F. Technetium-99m泭捧,捧-Bis(2-mercapto-2-methylpropyl)-2-aminobenzylamine: Technetium-99m Complexes of a Novel Bis(aminoethanethiol) Ligand泭J. Med. Chem.泭1994,泭37, 32823288. []
6.泭泭Liu, B.-L.; Meng, Z.-X.; Zhang, X.-X.; Li, L. Study on Structure-Activity Relationship of Cholesterol Analogs as Adrenal Imaging Agent with CNDO/2 Method泭J. Isotopes泭1992,泭5, 1.
5.泭泭Zhang, X.-X.; Liu, B.-L. The Structure-Activity Relationship of Cholesterol Analogs as Adrenal Imaging Agents泭J. Isotopes泭1991,泭4, 234.
4.泭泭Zhang, X.-X.; Liu, B.-L. New Cholesterol Analog as Adrenal Imaging Agent-Synthesis and Tissue Distribution of Bromine-82 Labeled 6-Bromomethylcholesterol泭J. Nucl. Radiochem.泭1991,泭13, 49. []
3.泭泭Zhang, X.-X.; Liu, B.-L.; Jin, Y.-T.; Kung, H. F. Development of Tc-99m-ECD as a New Brain Imaging Agent II. Kinetics of Ligand Exchange, Stability and Clinical Evaluation泭J. Isotopes泭1990,泭3, 137.
2.泭泭Zhang, X.-X.; Liu, B.-L.; Jin, Y.-T.; Kung, H. F. Development of Tc-99m-ECD as a New Brain Imaging Agent I. Synthesis and Labeling泭J. Isotopes泭1990,泭3, 73.
1.泭泭Pan, Z.-Y.; Jin, Y.-T.; Liu, B.-L.; Zhang, X.-X. Monkey and Human SPECT rCBF Imaging with Tc-99m-ECD泭J. Nucl. Med.泭1989,泭9, 210.